A Study on Spontaneous Ignition of Hydroxy Propyl Methyl Cellulose

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Fire Science and Engineering 2001;15(4):34-40.
Published online December 31, 2001.

Hydroxy Propyl Methyl Cellulose의 자연발화에 관한 연구

최재욱목연수하동명

¹부경대학교 안전공학과²부경대학교 안전공학과³세명대학교 안전공학과

A Study on Spontaneous Ignition of Hydroxy Propyl Methyl Cellulose

요약

HPMC의 자연발화는 일정한 주위온도에서 자연발화의 연구와 Godbret-Greenwald가 고안한 전기로에서 운상상태의 최소발화온도를 구하였으며, 시료를 용기에 충전했을 경우 용기의 크기가 클수록 발화한계 온도는 낮아졌으며 겉보기활성화에너지는 Frank-Kamenetskii의 열발화이론으로부터 계산하였고, 운상상태의 발화온도는 21%의 산소농도하에서 최소발화온도를 구하였으며, 산소농도 변화의 실험결과 산소농도 10%에서 발화되지 않았으며 한계산소농도를 구할 수 있었다.

Abstract

The spontaneous ignition of hydroxypropyl methyl cellulose(HPMC) was investigated at constant ambient temperature in the oven and minimum ignition temperature of dust clouds with Godbret-Creenwald Furnace respectively, In the experiments of the vessel filled with sample. the larger the vessel was the lower the spontaneous ignition temperature and ambient temperature was calculated from the Frank-Kamenetskii thermal ignition theory. The minimum ignition temperature for the dust cloud state was found under 21% oxygen concentration. At the experiment with the change of oxygen concentration, HPMC was not ignite at 10% $O_2$and so the limiting oxygen concentration was obtained at 10%.

Key Words: Spontaneous ignition, Ambient temperature, Minimum ignition temperature, Frank-kamenetskii thermal ignition theory